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   Double-layer capacitors (storage technology)  evaluated  
Double-layer capacitors (also termed "supercapacitors" or "ultracapacitors") store energy in the electric field of an electrochemical double-layer. The use of high surface-area electrodes results in an extremely large capacitance. The power and energy densities make capacitors an option for brake energy storage in rail vehicles.
Technology field: Regenerative braking and energy management
open main section General information
close main section General criteria
  close sub-section Status of development: test series
    Several projects are actually running in the field of transportation applications, e.g. tram supply without catenary and voltage drop compensation for weak distribution networks.
  Time horizon for broad application: 5 - 10 years
    (no details available)
  Expected technological development: highly dynamic
   

The main development goals for double-layer capacitor are

  • long lifetime
  • increase of the rated voltage
  • improvement of the range of operating temperature
  • increase of the energy and power densities.

According to Montena, the rated voltage will be increased up to 3 V within the next years. To easily access automotive applications a temperatures range from –35 up to 105 °C seems realistic. Montena fixes energy and power density goals for double-layer technology at 10 Wh/kg and 10 kW/kg.

From on-going research and development, Montena expects an increase of the electrolyte decomposition voltage and ionic conductance, an increase of the electrode accessible surface, chemical and mechanical stability as well as electronic conductance and the separator electronic insulation level and ionic conductance. A main activity lies in the development of new electrolytes based on the combination of novel organic solvents and improved conduction salts, permitting not only a higher rated voltage and a higher conductivity but also a larger operating temperature range.

    Motivation:
    If used as a storage technology for braking energy, the motivation is saving energy. Other possible applications include the catenary-free operation of city trams.
  Benefits (other than environmental): not applicable
    Depends on application context. Cf. Stationary energy storage in DC systems, Diesel-electric vehicles with energy storage and On-board energy storage in DC systems.
  Barriers: medium
   

State of development

Double-layer capacitors are only starting to become a mature and reliable technology.

    Success factors:
    Depends on application context. Cf. Stationary energy storage in DC systems, Diesel-electric vehicles with energy storage and On-board energy storage in DC systems.
  Applicability for railway segments: medium
    Type of traction:  electric - DC
    Type of transportation:  passenger - regional lines, passenger - suburban lines
   

As can be seen from Figure 4 the performance of double-layer capacitors is fitted for the range from light rail vehicles to regional trains.

Figure 4: Ragone diagram and charging times (corresponding to braking times of different trains)

Ragone-diagram_trains.gif

Source: IZT, data mainly from: Hentschel et al. 2000

    Grade of diffusion into railway markets:
  Diffusion into relevant segment of fleet: 0 %
  Share of newly purchased stock: 0 %
    (no details available)
  Market potential (railways): low
    (no details available)
    Example:
    Stationary storage system in urban transport network Cologne
open main section Environmental criteria
open main section Economic criteria
open main section Application outside railway sector
open main section Overall rating
References / Links:  Avart, Chabas 2001;  Caputo 2000;  Charvet 2001;  Hennig, Stephanblome 2000;  Kötz, Carlen 2000;  Schneuwly et al. 2002
Attachments:
Related projects:  Studies performed on energy storage systems;  THALES: hybrid tram train with on-board ultracapacitors
Contact persons:
 date created: 2002-10-09
 
 
© UIC - International Union of Railways 2003
 
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